7,646 research outputs found
Oscillatory processes in the theory of particulate formation in supersaturated chemical solutions
We study a nonlinear problem which occurs in the theory of particulate formation in supersaturated chemical solutions. Mathematically, the problem involves the bifurcation of time-periodic solutions in an initial-boundary value problem involving a nonlinear integro-differential equation. The mechanism controlling the oscillatory states is revealed by combining the theory of characteristics for first order partial differential equations with the multi-time scale perturbation analysis of a certain third order system of nonlinear ordinary differential equations
Bifurcation of Localized Disturbances in a Model Biochemical Reaction
Asymptotic solutions are presented to the nonlinear parabolic reaction-diffusion equations describing a model biochemical reaction proposed by I. Prigogine. There is a uniform steady state which, for certain values of the adjustable parameters, may be unstable. When the uniform solution is slightly unstable, the two-timing method is used to find the bifurcation of new solutions of small amplitude. These may be either nonuniform steady states or time-periodic solutions, depending on the ratio of the diffusion coefficients. When one of the parameters is allowed to depend on space and the basic state is unstable, it is found that the nonuniform steady state which is approached may show localized spatial oscillations. The localization arises out of the presence of turning points in the linearized stability equations
Non- Mn-driven ferroelectricity in antiferromagnetic BaMnO
Using first-principles density functional theory we predict a ferroelectric
ground state -- driven by off-centering of the magnetic Mn ion -- in
perovskite-structure BaMnO.
Our finding is surprising, since the competition between energy-lowering
covalent bond formation, and energy-raising
Coulombic repulsions usually only favors off-centering on the perovskite
-site for non-magnetic ions.
We explain this tendency for ferroelectric off-centering by analyzing the
changes in electronic structure between the centrosymmetric and polar states,
and by calculating the Born effective charges; we find anomalously large values
for Mn and O consistent with our calculated polarization of 12.8 C/cm.
Finally, we suggest possible routes by which the perovskite phase may be
stabilized over the usual hexagonal phase, to enable a practical realization of
a single-phase multiferroic.Comment: 6 pages, 3 figure
Rotations and Abundances of Blue Horizontal-Branch Stars in Globular Cluster M15
High-resolution optical spectra of eighteen blue horizontal-branch (BHB)
stars in the globular cluster M15 indicate that their stellar rotation rates
and photospheric compositions vary strongly as a function of effective
temperature. Among the cooler stars in the sample, at Teff ~ 8500 K, metal
abundances are in rough agreement with the canonical cluster metallicity, and
the v sin i rotations appear to have a bimodal distribution, with eight stars
at v sin i < 15 km/s and two stars at v sin i ~ 35 km/s. Most of the stars at
Teff > 10000 K, however, are slowly rotating, v sin i < 7 km/s, and their iron
and titanium are enhanced by a factor of 300 to solar abundance levels.
Magnesium maintains a nearly constant abundance over the entire range of Teff,
and helium is depleted by factors of 10 to 30 in three of the hotter stars.
Diffusion effects in the stellar atmospheres are the most likely explanation
for these large differences in composition. Our results are qualitatively very
similar to those previously reported for M13 and NGC 6752, but with even larger
enhancement amplitudes, presumably due to the increased efficiency of radiative
levitation at lower intrinsic [Fe/H]. We also see evidence for faster stellar
rotation explicitly preventing the onset of the diffusion mechanisms among a
subset of the hotter stars.Comment: 11 pages, 1 figure, 1 table, accepted to ApJ
Striking Photospheric Abundance Anomalies in Blue Horizontal-Branch Stars in Globular Cluster M13
High-resolution optical spectra of thirteen blue horizontal-branch (BHB)
stars in the globular cluster M13 show enormous deviations in element
abundances from the expected cluster metallicity. In the hotter stars (T_eff >
12000 K), helium is depleted by factors of 10 to 100 below solar, while iron is
enhanced to three times the solar abundance, two orders of magnitude above the
canonical metallicity [Fe/H] ~= -1.5 dex for this globular cluster. Nitrogen,
phosphorus, and chromium exhibit even more pronounced enhancements, and other
metals are also mildly overabundant, with the exception of magnesium, which
stays very near the expected cluster metallicity. These photospheric anomalies
are most likely due to diffusion --- gravitational settling of helium, and
radiative levitation of the other elements --- in the stable radiative
atmospheres of these hot stars. The effects of these mechanisms may have some
impact on the photometric morphology of the cluster's horizontal branch and on
estimates of its age and distance.Comment: 11 pages, 1 Postscript figure, uses aaspp4.sty, accepted for
publication in ApJ Letter
Time Averaged Quantum Dynamics and the Validity of the Effective Hamiltonian Model
We develop a technique for finding the dynamical evolution in time of an
averaged density matrix. The result is an equation of evolution that includes
an Effective Hamiltonian, as well as decoherence terms in Lindblad form.
Applying the general equation to harmonic Hamiltonians, we confirm a previous
formula for the Effective Hamiltonian together with a new decoherence term
which should in general be included, and whose vanishing provides the criteria
for validity of the Effective Hamiltonian approach. Finally, we apply the
theory to examples of the AC Stark Shift and Three- Level Raman Transitions,
recovering a new decoherence effect in the latter.Comment: 7 pages, 2 figure
Eyes wide shut? UK consumer perceptions on aviation climate impacts and travel decisions to New Zealand
The purview of climate change concern has implicated air travel, as evidenced in a growing body of academic literature concerned with aviation CO2 emissions. This article assesses the relevance of climate change to long haul air travel decisions to New Zealand for United Kingdom consumers. Based on 15 semi-structured open-ended interviews conducted in Bournemouth, UK during June 2009, it was found that participants were unlikely to forgo potential travel decisions to New Zealand because of concern over air travel emissions. Underpinning the interviewees’ understandings and responses to air travel’s climate impact was a spectrum of awareness and attitudes to air travel and climate change. This spectrum ranged from individuals who were unaware of air travel’s climate impact to those who were beginning to consume air travel with a ‘carbon conscience’. Within this spectrum were some who were aware of the impact but not willing to change their travel behaviours at all. Rather than implicating long haul air travel, the empirical evidence instead exemplifies changing perceptions towards frequent short haul air travel and voices calls for both government and media in the UK to deliver more concrete messages on air travel’s climate impact
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